全文获取类型
收费全文 | 6207篇 |
免费 | 609篇 |
国内免费 | 542篇 |
专业分类
化学 | 1376篇 |
晶体学 | 23篇 |
力学 | 815篇 |
综合类 | 52篇 |
数学 | 1479篇 |
物理学 | 3613篇 |
出版年
2023年 | 63篇 |
2022年 | 81篇 |
2021年 | 151篇 |
2020年 | 161篇 |
2019年 | 164篇 |
2018年 | 160篇 |
2017年 | 176篇 |
2016年 | 187篇 |
2015年 | 201篇 |
2014年 | 247篇 |
2013年 | 511篇 |
2012年 | 240篇 |
2011年 | 295篇 |
2010年 | 210篇 |
2009年 | 323篇 |
2008年 | 364篇 |
2007年 | 400篇 |
2006年 | 380篇 |
2005年 | 303篇 |
2004年 | 273篇 |
2003年 | 272篇 |
2002年 | 297篇 |
2001年 | 295篇 |
2000年 | 284篇 |
1999年 | 218篇 |
1998年 | 161篇 |
1997年 | 149篇 |
1996年 | 91篇 |
1995年 | 106篇 |
1994年 | 82篇 |
1993年 | 77篇 |
1992年 | 64篇 |
1991年 | 55篇 |
1990年 | 27篇 |
1989年 | 32篇 |
1988年 | 29篇 |
1987年 | 32篇 |
1986年 | 19篇 |
1985年 | 24篇 |
1984年 | 23篇 |
1983年 | 9篇 |
1982年 | 17篇 |
1981年 | 14篇 |
1980年 | 7篇 |
1979年 | 18篇 |
1978年 | 8篇 |
1977年 | 13篇 |
1976年 | 7篇 |
1973年 | 14篇 |
1972年 | 6篇 |
排序方式: 共有7358条查询结果,搜索用时 187 毫秒
41.
Joseelyne G. Hernández‐Lima Jose E. Barquera‐Lozada Gabriel Cuevas Fernando Cortés‐Guzmán 《Journal of computational chemistry》2015,36(21):1573-1578
The normal and reverse Perlin effect is usually explained by the redistribution of electron density produced by hyperconjugative mechanisms, which increases the electron population within axial or equatorial proton in normal or reverse effect, respectively. Here an alternative explanation for the Perlin effect is presented on the basis of the topology of the induced current density, which directly determines the nuclear magnetic shielding. Current densities around the C? H bond critical point and intra‐atomic and interatomic contributions to the magnetic shielding explain the observed Perlin effect. The balance between intra‐atomic and interatomic contributions determines the difference in the total atomic shielding. Normal Perlin effect is dominated by intra‐atomic part, whereas reverse effect is dominated by interatomic contribution. © 2015 Wiley Periodicals, Inc. 相似文献
42.
Methoxy and Methyl Group Rotation: Solid‐State NMR 1H Spin‐Lattice Relaxation,Electronic Structure Calculations,X‐ray Diffractometry,and Scanning Electron Microscopy 下载免费PDF全文
Prof. Peter A. Beckmann Dr. Clelia W. Mallory Prof. Frank B. Mallory Prof. Arnold L. Rheingold Dr. Xianlong Wang 《Chemphyschem》2015,16(7):1509-1519
We report solid‐state 1H nuclear magnetic resonance (NMR) spin‐lattice relaxation experiments, X‐ray diffractometry, field‐emission scanning electron microscopy, and both single‐molecule and cluster ab initio electronic structure calculations on 1‐methoxyphenanthrene ( 1 ) and 3‐methoxyphenanthrene ( 2 ) to investigate the rotation of the methoxy groups and their constituent methyl groups. The electronic structure calculations and the 1H NMR relaxation measurements can be used together to determine barriers for the rotation of a methoxy group and its constituent methyl group and to develop models for the two coupled motions. 相似文献
43.
Multicomponent Molecular Orbital–Climbing Image–Nudged Elastic Band Method to Analyze Chemical Reactions Including Nuclear Quantum Effect 下载免费PDF全文
To analyze the H/D isotope effects on hydrogen transfer reactions in XHCHCHCHY?XCHCHCHYH (X, Y=O, NH, or CH2) including the nuclear quantum effect of proton and deuteron, we propose a multicomponent molecular orbital‐climbing image‐nudged elastic band (MC_MO–CI–NEB) method. We obtain not only transition state structures but also minimum‐energy paths (MEPs) on the MC_MO effective potential energy surface by using MC_MO–CI–NEB method. We find that nuclear quantum effect affects not only stationary‐point geometries but also MEPs and electronic structures in the reactions. We clearly demonstrate the importance of including nuclear quantum effects for H/D isotope effect on rate constants (kH/kD). 相似文献
44.
45.
The translation behaviors of oscillating bubbles are closely related to the polymerizations and dispersions between them, which are crucial for the ultrasonic cavitation effect. In this study, six types of translational motion of bubbles with a wide range of sizes (2–100 μm) in the R01-R02 plane are investigated. Our results demonstrate that in addition (to the 2nd order harmonic), the 1/2 order subharmonic can change the bubble pairs from the three states of the attraction, stable after attraction, and repulsion to that of the repulsion, coalescence, and attraction, respectively. Furthermore, within the range of the main resonance radius and the 1/2 order subharmonic resonance radius, the chaotic bubble pairs with alternating attractive and repulsive forces appear in the region between the coalescence pairs and stable pairs after attraction. Finally, the corresponding physical mechanisms of the chaotic translational motions are also revealed. 相似文献
46.
47.
Mixed Quantum Classical Reaction Rates based on the Phase Space Formulation of the Hierarchical Equations of Motion 下载免费PDF全文
In a previous work [J. Chem. Phys. 140 , 174105 (2014)], we have shown that a mixed quantum classical (MQC) rate theory can be derived to investigate the quantum tunneling effects in the proton transfer reactions. However, the method is based on the high temperature approximation of the hierarchical equation of motion (HEOM) with the Debye-Drude spectral density, and results in a multi-state Zusman type of equation. We now extend this theory to include quantum effects of the bath degrees of freedom. By writing the full HEOM into a multidimensional partial differential equation in phase space, we can define a new reaction coordinate, and the previous method can be generalized to the full quantum regime. The validity of the new method is demonstrated by using numerical examples, including the spin-Boson model, and the double well model for proton transfer reaction. The new method is found to resolve some key problems of the previous theory based on high temperature approximation, including possible numerical instability in long time simulation and wrong rate constant at low temperatures. 相似文献
48.
Mechanistic studies promote scientific development from phenomena to theories.Aggregation-induced emission(AIE),as an unusual photophysical phenomenon,builds the bridge between molecular science and aggregate mesoscience.With the twenty-year development of AIE,restriction of intramolecular motion(RIM)has been verified as the working mechanism of AIE effect.In this review,these mechanistic works about RIM are summarized from experimental and theoretical perspectives.Thereinto,the experimental studies are introduced from three parts:external rigidification,structural modification and structural characterization.In the theoretical part,calculations on the low-frequency motion of AIEgens have been performed to prove the RIM mechanism.By virtue of the theoretical calculations,some new mechanisms are proposed to supplement the RIM,such as restriction of access to conical intersection,suppression of Kasha transition,restriction of access to dark state,etc.It is foreseeable that the RIM mechanism will unify the photophysical theories for both molecules and aggregates,and inspire more progress in aggregate science. 相似文献
49.
应用主成分分析(Principal component analysis,PCA)和聚类分析法(Cluster analysis,CA)对9种(27个)常见食用植物油及100个餐饮废油的低场核磁共振(Low-field nuclear magnetic resonance,LF-NMR)(T2)弛豫特性数据进行分析。结果表明:在正常食用油种类区分方面,主成分分析的效果较优,9种食用油在主成分分布图上按种类正确分组,边界清晰。而在正常食用油与餐饮废油的区分方面,聚类分析效果较优,引入30个待测样本后,聚类分析(127个样品,欧式距离=5)的正确率为94.49%,分析误判率为5.51%,分组效果良好。LF-NMR结合化学模式识别可实现对油脂种类及餐饮废弃油脂的鉴别。 相似文献
50.
采用魔角旋转固体核磁碳谱法(MAS–~(13)CNMR)测定硫化丁苯橡胶中的苯乙烯含量。通过固体核磁碳谱解析,对丁苯橡胶中苯乙烯、1,2-乙烯基、1,4-丁二烯的特征峰进行归属分析,以固体核磁外标法定量。对已知苯乙烯含量的标准样品进行测定,绘制校正曲线,结果显示理论苯乙烯含量与固体核磁法计算结果成良好的线性关系,线性相关系数(r~2)为0.97。经标准曲线校正后的苯乙烯含量接近于真实值,计算结果的相对误差小于5%,测定结果的相对标准偏差为0.31%(n=6)。该方法适用于单一胶种的硫化丁苯橡胶中苯乙烯含量的检测。 相似文献